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翻訳と辞書　辞書検索 [ 開発暫定版 ] スポンサード リンク Thiol-ene reaction ： ウィキペディア英語版 Thiol-ene reaction The thiol-ene reaction (also alkene hydrothiolation) is an organic reaction between a thiol and an alkene to form an alkyl sulfide. This reaction was first reported in 1905, but it gained prominence in the late 1990s and early 2000s for its feasibility and wide range of applications.〔Lowe, A. B. ''Polymer Chemistry'' 2010, 1 (1), 17–36. DOI: (10.1039/B9PY00216B )〕〔Nilsson, C.; Simpson, N.; Malkoch, M.; Johansson, M.; Malmstrom, E. ''Journal of Polymer Science: Part A: Polymer Chemistry'' 2008, 46, 1339-1348. DOI: (1002/pola.22474 )〕 This reaction is accepted as a click chemistry reaction given the reactions’ high yield, stereoselectivity, high rate, and thermodynamic driving force. The reaction results in a anti-Markovnikov addition of a thiol compound to an alkene. Given the stereoselectivity, high rate and yields, this reaction is synthetically useful for organic chemists. Thiol-ene reactions have numerous applications in material and biomedical sciences.〔〔Hoyle, C. E.; Bowman, C. N. ''Agewandte Chemie International Edition'' 2010, 49 (9), 1540–1573. DOI: (10.1002/anie.200903924 )〕 ==Mechanisms== 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「Thiol-ene reaction」の詳細全文を読む スポンサード リンク 翻訳と辞書 : 翻訳のためのインターネットリソース Copyright(C) kotoba.ne.jp 1997-2016. All Rights Reserved.